Hello,
It is logical to impose a free surface elevation and a constant tracer density as boundary conditions. In such kind of models, we proceed exactly by the same manner. However, there is 2 important remarks for your case:
1- To impose the water elevation and a constant tracer density, you have to verify that the boundary is located far enough of the embouchure of the river. This will ensure that the velocity field is dumped enough in the vicinity of the boundary compared to the one in the river/estuary. This condition is necessary; otherwise, you need to prescribe a Thompson boundary condition which is not recommanded in your case. Thus, the solution, in my opinion is to make an extension of your madel by adding a sea area with an increasing coarse mesh. This will permit to Telemac to impose smoothly the prescribed BC.
2- Based on my humble experience, it is important to include tide effects for this kind of application. Moreover, I don't know if you have some measurements, but, very often, the salinity is not constant and it decreases due to the big quantity of incoming fresh water.
I hope that this is helpful
Riadh